ATOMIC FORCE MICROSCOPY: DIFFERENT APPROACH TO DISCOVER THE PAPER

Authors

  • Dana-Maria Copolovici Institute of Research, Development, and Innovation in Technical and Natural Sciences of “Aurel Vlaicu” University-Romania
  • Grigore Craciun Institute of Research, Development, and Innovation in Technical and Natural Sciences of “Aurel Vlaicu” University-Romania
  • Cecilia Sîrghie Institute of Research, Development, and Innovation in Technical and Natural Sciences of “Aurel Vlaicu” University-Romania

Abstract

Natural fibers were used as material in paper industry for centuries and then their use decayed. Currently, it is considered a new normal course to include natural fibres in the technology of production of paper as resource with high potential to be available in many countries, especially where the wood is not available. Paper sheets containing pulp from second category fibers, SCF, consisting of a mixture of bleached pulp of very short cotton fibers and chemical degumming hemp tow and respectively, from long wooden kraft, were attained. In the bleaching procedure of SCF was used peroxide delignification procedure, in the presence of a polyoxometalate (Na2H3PMo10V2O40) as oxidative reagent, in aqueous solution. Paper sheets containing bleached long wooden kraft were also obtained. Mechanical, optical, and surface characteristics (atomic force microscopy) analyses of these two types of paper sheets were determined to evaluate the possible application of the SCF to be used in paper industry.

References

Hong, F.; Guo, X.; Zhang, S.; Han, S.-f.; Yang, G.; Jonsson, L. J. Bacterial cellulose production from cotton-based waste textiles: Enzymatic saccharification enhanced by ionic liquid pretreatment. Bioresource Technol. 2012, 104, 503-508.

Chuayjuljit, S.; Su-Uthai, S.; Tunwattanaseree, C.; Charuchinda, S. Preparation of Microcrystalline Cellulose from Waste-Cotton Fabric for Biodegradability Enhancement of Natural Rubber Sheets. J. Reinf. Plast. Comp. 2009, 28, 1245-1254.

Ratanakamnuan, U.; Atong, D.; Aht-Ong, D. Cellulose esters from waste cotton fabric via conventional and microwave heating. Carbohyd. Polym. 2012, 87, 84-94.

Xiong, R.; Zhang, X.; Tian, D.; Zhou, Z.; Lu, C. Comparing microcrystalline with spherical nanocrystalline cellulose from waste cotton fabrics. Cellulose 2012, 19, 1189-1198.

Bujanovic, B.; Ralph, S.; Reiner, R.; Hirth, K.; Atalla, R. Polyoxometalates in Oxidative Delignification of Chemical Pulps: Effect on Lignin. Materials 2010, 3, 1888-1903.

Gamelas, J. A. F.; Evtyugina, M. G.; Portugal, I.; Evtuguin, D. V. New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications. RSC Advances 2012, 2, 831-839.

Gaspar, A.; Evtuguin, D. V.; Neto, C. P. Oxygen bleaching of kraft pulp catalysed by Mn(III)-substituted polyoxometalates. Appl. Catal. A-Gen. 2003, 239, 157-168.

Weinstock, I. A.; Hammel, K. E.; Moen, M. A.; Landucci, L. L.; Ralph, S.; Sullivan, C. E.; Reiner, R. S. Selective transition-metal catalysis of oxygen delignification using water-soluble salts of polyoxometalate (POM) anions. Part II. Reactions of alpha-[SiVW11O40](5-) with phenolic lignin-model compounds. Holzforschung 1998, 52, 311-318.

Balakshin, M. Y.; Evtuguin, D. V.; Neto, C. P.; Cavaco-Paulo, A. Polyoxometalates as mediators in the laccase catalyzed delignification. J. Mol. Catal. B-Enzym. 2001, 16, 131-140.

Weinstock, I. A.; Barbuzzi, E. M. G.; Wemple, M. W.; Cowan, J. J.; Reiner, R. S.; Sonnen, D. M.; Heintz, R. A.; Bond, J. S.; Hill, C. L. Equilibrating metal-oxide cluster ensembles for oxidation reactions using oxygen in water. Nature 2001, 414, 191-195.

Marques, G.; Gamelas, J. A. F.; Ruiz-Duenas, F. J.; del Rio, J. C.; Evtuguin, D. V.; Martinez, A. T.; Gutierrez, A. Delignification of eucalypt kraft pulp with manganese-substituted polyoxometalate assisted by fungal versatile peroxidase. Bioresource Technol. 2010, 101, 5935-5940.

Gamelas, J. A. F.; Tavares, A. P. M.; Evtuguin, D. V.; Xavier, A. M. B. Oxygen bleaching of kraft pulp with polyoxometalates and laccase applying a novel multi-stage process. J. Mol. Catal. B-Enzym. 2005, 33, 57-64.

Binnig, G.; Quate, C. F.; Gerber, C. Atomic force microscope. Phys. Rev. Lett. 1986, 56, 930-933.

Hanley, S. J.; Giasson, J.; Revol, J. F.; Gray, D. G. Atomic force microscopy of cellulose microfibrils - comparison with transmission electron-microscopy. Polymer 1992, 33, 4639-4642.

Olszewska, A.; Eronen, P.; Johansson, L.-S.; Malho, J.-M.; Ankerfors, M.; Lindstrom, T.; Ruokolainen, J.; Laine, J.; Osterberg, M. The behaviour of cationic NanoFibrillar Cellulose in aqueous media. Cellulose 2011, 18, 1213-1226.

Stiernstedt, J.; Nordgren, N.; Wagberg, L.; Brumer, H., III; Gray, D. G.; Rutland, M. W. Friction and forces between cellulose model surfaces: A comparison. J. Colloid Interf. Sci. 2006, 303, 117-123.

Eronen, P.; Österberg, M.; Jaaskelainen, A.-S. Effect of alkaline treatment on cellulose supramolecular structure studied with combined confocal Raman spectroscopy and atomic force microscopy. Cellulose 2009, 16, 167-178.

Liu, H.; Fu, S.; Zhu, J. Y.; Li, H.; Zhan, H. Visualization of enzymatic hydrolysis of cellulose using AFM

phase imaging. Enzyme Microb. Tech. 2009, 45, 274-281.

Österberg, M.; Schmidt, U.; Jaaskelainen, A.-S. Combining confocal Raman spectroscopy and atomic force microscopy to study wood extractives on cellulose surfaces. Colloid. Surfaces A 2006, 291, 197-201.

Le Troedec, M.; Rachini, A.; Peyratout, C.; Rossignol, S.; Max, E.; Kaftan, O.; Fery, A.; Smith, A. Influence of chemical treatments on adhesion properties of hemp fibres. J. Colloid Interf. Sci. 2011, 356, 303-310.

Eronen, P.; Österberg, M.; Heikkinen, S.; Tenkanen, M.; Laine, J. Interactions of structurally different hemicelluloses with nanofibrillar cellulose. Carbohyd. Polym. 2011, 86, 1281-1290.

Sirghie, C.; Popa, N.; Turcu, F. Romania 119961B1/2005, 2005; Vol. Brevet 119961B1/2005.

Evtuguin, D. V.; Neto, C. P.; De Jesus, J. D. P. Bleaching of kraft pulp by oxygen in the presence of polyoxometalates. J. Pulp Pap. Sci. 1998, 24, 133-140.

Evtuguin, D. V.; Neto, C. P.; Marques, V. M. In Iswpc - 9th International Symposium on Wood and Pulping Chemistry - Poster Presentations, 1997.

Weinstock, I. A.; Atalla, R. H.; Reiner, R. S.; Moen, M. A.; Hammel, K. E.; Houtman, C. J.; Hill, C. L.; Harrup, M. K. A new environmentally benign technology for transforming wood pulp into paper - Engineering polyoxometalates as catalysts for multiple processes. J. Mol. Catal. A-Chem. 1997, 116, 59-84.

Downloads

Published

2013-10-31